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29.09 - ¿¡Å׸£¡¤¿¡Å׸£¾ËÄڿ᤿¡Å׸£Æä³î¡¤¿¡Å׸£¾ËÄÚ¿ÃÆä³î¡¤°ú»êÈ­¾ËÄڿᤰú»êÈ­¿¡Å׸£¡¤°ú»êÈ­¾Æ¼¼Å»°ú °ú»êÈ­Çì¹Ì¾Æ¼¼Å»¡¤°ú»êÈ­ÄÉÅæ(È­ÇÐÀûÀ¸·Î ´ÜÀÏÇÑ °ÍÀÎÁö¿¡ »ó°ü¾ø´Ù)°ú À̵éÀÇ ÇҷΰÕÈ­À¯µµÃ¼¡¤¼úÆùÈ­À¯µµÃ¼¡¤´ÏÆ®·ÎÈ­À¯µµÃ¼¡¤´ÏÆ®·Î¼ÒÈ­À¯µµÃ¼

(A) ¿¡Å׸£(ether)
¿¡Å׸£(ether)´Â ¼ö»ê±âÀÇ ¼ö¼Ò¿øÀÚ°¡ źȭ¼ö¼Ò±â[¾Ëų(alkyl)À̳ª ¾Æ¸±(aryl)]·Î ġȯµÈ ¾ËÄÚ¿ÃÀ̳ª Æä³î(phenol)·Î °£ÁÖÇϸç ÀϹݽÄÀº(R-O-R1)À̸ç R°ú R1Àº °°À» ¶§µµ ÀÖ°í °°Áö ¾ÊÀ» ¶§µµ ÀÖ´Ù.
ÀÌµé ¿¡Å׸£(ether)´Â ¸Å¿ì ¾ÈÁ¤ÇÑ Áß¼º ¹°ÁúÀÌ´Ù.
źȭ¼ö¼ÒÀÇ ±â°¡ ºñȯ½Ä°è¿­¿¡ ¼ÓÇÑ´Ù¸é ¿¡Å׸£(ether)µµ ¿ª½Ã ºñȯ½ÄÀ̸ç; ȯ½Ä±â´Â ȯ½Ä¿¡Å׸£(cyclic ether)°¡ µÈ´Ù.
ºñȯ½Ä°è¿­ÀÇ Ã¹ ¹ø° ¿¡Å׸£´Â °¡½º »óÅÂÀÌ¸ç ±× ¹ÛÀÇ °ÍÀº ¿¡Å׸£ÀÇ Æ¯À¯ÀÇ ³¿»õ¸¦ °®´Â Èֹ߼º ¾×üÀ̸ç; ź¼Ò¼ö°¡ ¸¹Àº °ÍÀº ¾×ü³ª °íüÀÌ´Ù.

(¥°) ´ëĪºñȯ½Ä ¿¡Å׸£(symmetrical acyclic ether)

(1) µð¿¡Æ¿¿¡Å׸£(diehtyl ether)(C2H5OC2H5) : Ư¼öÇÏ°Ô Å¸´Â µíÇÑ ³¿»õ¸¦ Áö´Ñ ¹«»ö ±¼Àý¼ºÀÇ ¾×ü·Î¼­; Èֹ߼ºÀÌ °­ÇÏ°í °¡¿¬¼ºÀÌ ¸Å¿ì ³ôÀº ¹°ÁúÀÌ´Ù. ¸¶ÃëÁ¦¿Í À¯±â ÇÕ¼º¿¡ »ç¿ëÇÑ´Ù.

(2) µð(Ŭ·Î·Î¿¡Æ¿)¿¡Å׸£[di(chloroethyl) ether]³ª µðŬ·Î·Îµð¿¡Æ¿¿¡Å׸£(dichlorodiethyl ether)

(3) µðÀ̼ÒÇÁ·ÎÇÊ ¿¡Å׸£(di-isopropyl ether)

(4) µðºÎÆ¿¿¡Å׸£(dibutyl ether)

(5) µðÆæÆ¿¿¡Å׸£(µð¾Æ¹Ð¿¡Å׸£)[dipentyl ether(diamyl ether)]

(¥±) ºñ´ëĪºñȯ½Ä ¿¡Å׸£(non symmetrical acyclic ether)

(1) ¿¡Æ¿¸ÞÆ¿¿¡Å׸£(ethyl methyl ether)

(2) ¿¡Æ¿À̼ÒÇÁ·ÎÇÊ¿¡Å׸£(ethyl isopropyl ether)

(3) ºÎÆ¿¿¡Æ¿¿¡Å׸£(butyl ethyl ether)

(4) ÆæÆ¿¿¡Æ¿¿¡Å׸£(pentyl ethyl ether)

(¥²) Æ÷È­Áöȯ½Ä(cyclanic)¡¤ºÒÆ÷È­Áöȯ½Ä(cyclenic)°ú ½ÃŬ·ÎÅ׸£Ææ(cycloterpenic) ¿¡Å׸£

(¥³) ¹æÇâÁ·(Û»úÅðé) ¿¡Å׸£(aromatic ether)

(1) ¾Æ´Ï¼Ö(anisole)(C6H5OCH3) (¸ÞÆ¿Æä´Ò¿¡Å׸£)(methyl phenyl ether) : »óÄèÇÑ ³¿»õ¸¦ Áö´Ñ ¹«»öÀÇ ¾×ü·Î¼­; À¯±â ÇÕ¼º (¿¹: ÇÕ¼ºÇâ·á) ¿ø·á·Î ¾²ÀÌ¸ç ¿ëÁ¦(éÁð¥ : solvent)¿Í ±¸ÃæÁ¦·Îµµ »ç¿ëÇÑ´Ù.

(2) Æä³×Åç(¿¡Æ¿Æä´Ò¿¡Å׸£)[phenetole(ethyl phenyl ether)](C6H5OC2H5)

(3) µðÆä´Ò¿¡Å׸£(diphenyl ether)(C6H5OC6H5) : Á¦¶ó´½(geranium)°ú °°Àº ³¿»õ¸¦ Áö´Ñ ¹«»öÀÇ ¹Ù´Ã ¸ð¾ç °áÁ¤Ã¼·Î¼­; Çâ·á¿¡ »ç¿ëÇÑ´Ù.

(4) 1,2-µðÆä³ì½Ã¿¡Åº(¿¡Æ¿·»±Û¸®ÄÝ µðÆä´Ò¿¡Å׸£)[1,2-diphenoxyethane(ethylen glycol diphenyl ether)]

(5) ¾Æ³×Åç(anethole) : ¾Æ´Ï½º¿­¸ÅÀÇ ±â¸§(êú : aniseed oil)¿¡ ÇÔÀ¯µÇ¾î ÀÖ´Ù. ¼·¾¾ 20µµ ÀÌÇÏÀÇ ¿Âµµ¿¡¼­´Â ÀÛÀº °áÁ¤Ã¼À̸ç; ±× ÀÌ»óÀÇ ¿Âµµ¿¡¼­´Â °­ÇÑ ¾Æ´Ï½º¿­¸Å ±â¸§ÀÇ ³¿»õ¸¦ Áö´Ñ À¯µ¿¼ºÀÇ ¾×üÀÌ´Ù.

(6) µðº¥Áú¿¡Å׸£(dibenzyl ether)

(7) ´ÏÆ®·ÎÆä³×Åç(nitrophenetole) : Æä³×Åç(phenetole)ÀÇ ´ÏÆ®·ÎÈ­(nitrated) À¯µµÃ¼·Î¼­ ¿À¸£Åä´ÏÆ®·ÎÆä³×Åç(o-nitrophenetole)Àº Ȳ»öÀÇ ±â¸§(êú)ÀÌ°í ÆĶó´ÏÆ®·ÎÆä³×Åç(p-Nitrophenetole)Àº °áÁ¤ÀÌ´Ù.

(8) ´ÏÆ®·Î¾Æ´Ï¼Ö(nitroanisole) : ¾Æ´Ï¼Ö(anisole)ÀÇ ´ÏÆ®·ÎÈ­(nitrated) À¯µµÃ¼·Î¼­ ¿À¸£Åä´ÏÆ®·Î¾Æ´Ï¼Ö(o-nitroanisole)Àº ¾×üÀÌ°í ¸ÞŸ(m-)¿Í ÆĶó´ÏÆ®·Î¾Æ´Ï¼Ö(p-Nitroanisole)Àº ¾ãÀº ÆÇ ¸ð¾çÀÇ °áÁ¤Ã¼ÀÌ´Ù. Æ®¸®´ÏÆ®·Î¾Æ´Ï¼Ö(trinitroanisole)Àº ¸Å¿ì °­ÇÑ Æø¹ß¼º ¼ºÁúÀÌ´Ù.

(9) 2-ÅͼŸ®-ºÎÆ¿-5-¸ÞÆ¿-4,6-µð´ÏÆ®·Î¾Æ´Ï¼Ö(¸Ó½ºÅ© ¾Ïºê·¹Æ®)[2-tert-butyl-5-methyl-4,6-dinitroanisole(musk ambrette)] : ¾Ïºê·¹Æ®±â¸§(ambrette oil)°ú õ¿¬ »çÇâÀÇ ÇâÀ» Á¶ÇÕÇÑ È²»öÀÇ °áÁ¤Ã¼

(10) º£Å¸-³ªÇÁÆ¿¸ÞÆ¿°ú ¿¡Æ¿¿¡Å׸£(ÀÎÁ¶ ³×·Ñ¸® À¯)[¥â-naphthyl methyl and ethyl ether(artificial neroli oil)] : ¿À·»ÁöÈ­À¯¿Í ºñ½ÁÇÑ ³¿»õ¸¦ Áö´Ñ ¹«»öÀÇ °áÁ¤ °¡·çÀÌ´Ù.

(11) ¸ÞŸũ·¹Á¹°ú ºÎÆ¿¸ÞŸũ·¹Á¹ÀÇ ¸ÞÆ¿¿¡Å׸£(methyl ether of m-cresol and butyl-m-cresol)

(12) Æä´ÒÅ丱¿¡Å׸£(phenyl tolyl ether)

(13) µðÅ丱¿¡Å׸£(ditolyl ether)

(14) º¥Áú¿¡Æ¿¿¡Å׸£(benzyl ethyl ether)

(B) ¿¡Å׸£-¾ËÄÚ¿Ã(ether-alcohol)
À̵éÀº ´Ù°¡¾ËÄÚ¿Ã(polyhydric alcohols)À̳ª Æä³î¾ËÄÚ¿Ã(phenol-alcohols)ÀÌ Æä³î¼º ¼ö»ê±âÀÇ ¼ö¼Ò[Æä³î¾ËÄÚ¿Ã(phenol-alcohols)ÀÇ °æ¿ì]³ª ÇÑ °³ÀÇ ¾ËÄڿüº ¼ö»ê±âÀÇ ¼ö¼Ò[´Ù°¡¾ËÄÚ¿Ã(polyhydric alcohols)ÀÇ °æ¿ì]°¡ ¾Ëų(alkyl)À̳ª ¾Æ¸±(aryl)±â·Î ġȯµÇ¾î À¯µµµÈ °ÍÀÌ´Ù.

(1) 2,2'-¿Á½Ãµð¿¡Åº¿Ã(µð¿¡Æ¿·»±Û¸®ÄÝ, µð°ñ)[2,2'-oxydiethanol(diethylene glycol, digol)] : ¹«»öÀÇ ¾×ü·Î¼­; À¯±â ÇÕ¼º¿ø·á¡¤°Ë(gum)¡¤¼öÁöÀÇ ¿ëÁ¦(éÁð¥ : solvent)¡¤Æø¾à Á¦Á¶¿Í Çöó½ºÆ½ÀÇ Á¦Á¶¿¡ »ç¿ëÇÑ´Ù.

(2) ¿¡Æ¿·»±Û¸®ÄÝ(ethylene glycol)À̳ª µð¿¡Æ¿·»±Û¸®ÄÝ(diethyleneglycol)ÀÇ ¸ð³ë¸ÞÆ¿(monomethyl)¡¤¸ð³ë¿¡Æ¿(monoethyl)¡¤¸ð³ëºÎÆ¿(monobutyl)°ú ±× ¹ÛÀÇ ¸ð³ë¾Ëų¿¡Å׸£(monoalkylether)

(3) ¿¡Æ¿·»±Û¸®ÄÝ(ethylene glycol)À̳ª µð¿¡Æ¿·»±Û¸®ÄÝ(diethylene glycol)ÀÇ ¸ð³ëÆä´Ò¿¡Å׸£(monophenyl ether)

(4) ¾Æ´Ï½Ç¾ËÄÚ¿Ã(anisyl alcohol)

(5) ±¸¾ÆÀÌ¿¡Å丰(guaietolin)(INN)(±Û¸®¼¼·Ñ¸ð³ë(2-¿¡Åå½ÃÆä´Ò)¿¡Å׸£)[glycerol mono(2-ethoxyphenyl)ether)]¿Í ±¸¾ÆÀÌÆä³×½Å(guaifenesin)(INN)[±Û¸®¼¼·Ñ ¸ð³ë(2-¸ÞÅå½ÃÆä´Ò)¿¡Å׸£][glycerol mono(2-methoxyphenyl)ether)]

(C) ¿¡Å׸£Æä³î(ether-phenol)°ú ¿¡Å׸£¾ËÄÚ¿ÃÆä³î(ether-alcohol-phenol)
À̵éÀº 2°¡Æä³î(dihydric phenols)À̳ª Æä³î¾ËÄÚ¿Ã(phenol alcohols)ÀÌ ¾ËÄڿüº ¼ö»ê±â(alcohol hydroxyl group)ÀÇ ¼ö¼Ò[Æä³î¾ËÄÚ¿ÃÀÇ °æ¿ì]³ª ÇÑ °³ÀÇ Æä³î¼º ¼ö»ê±â(phenol hydroxyl group)ÀÇ ¼ö¼Ò[µðÈ÷µå¸¯ Æä³î(dihydric phenols)ÀÇ °æ¿ì]°¡ ¾Ëų(alkyl)À̳ª ¾Æ¸±(aryl)±â·Î ġȯÇÏ¿© À¯µµµÈ °ÍÀÌ´Ù.

(1) ±¸¾ÆÀ̾ßÄÝ(guaiacol)* : ³Êµµ¹ã³ª¹« Ÿ¸£(beech-wood tar)¿¡ Á¸ÀçÇÏ¸ç ¸ñ(ÙÊ) Å©·¹¿À¼ÒÆ®(wood creosote)ÀÇ ÁÖ¼ººÐÀÌ´Ù. Ư¼öÇÑ ¹æÇ⼺(Û»úÅàõ)À» Áö´Ñ ¹«»öÀÇ °áÁ¤Ã¼À̳ª; ÇÑ ¹ø ¿ëÇØÇÏ¸é ¾×ü »óÅ·ΠÀ¯ÁöµÈ´Ù. ÀǾà°ú À¯±â ÇÕ¼º¿¡ »ç¿ëÇÑ´Ù.

(2) ¼úÆ÷±¸¾ÆÀ̾ßÄÝ(INN) (±¸¾ÆÀ̾ßÄݼúÆù»êÄ®·ý)(potassium guaiacolsuphonate) : ¹Ì¼¼ °¡·ç·Î¼­ ÀǾà¿ëÀ¸·Î ±¤¹üÀ§ÇÏ°Ô »ç¿ëÇÑ´Ù.

(3) ¿ÀÀÌ°Ô³î(eugenol) : Á¤Çâ(clove)À¸·ÎºÎÅÍ ¾ò¾îÁö°í Ä«³×À̼ÇÀÇ ³¿»õ¸¦ °¡Áö´Â ¹«»ö ¾×üÀÌ´Ù.

(4) À̼ҿÀÀÌ°Ô³î(isoeugenol) : ¿ÀÀÌ°Ô³î·ÎºÎÅÍ ÇÕ¼ºÀ¸·Î ¾ò¾îÁö¸ç À°µÎ±¸(ë¿Ôå蔲 : nutmeg)À¯ÀÇ ¼ººÐÀÌ´Ù.

(5) ÇÇ·ÎÄ«Å×Äݸð³ë¿¡Æ¿¿¡Å׸£(±¸¾Æ¿¡Åç)[pyrocatechol monoethyl ether(guaethol)] : ½º¿þµ§¼Û¸ñÀ¯(swedish pine-wood oil)¿¡ Á¸ÀçÇÏ°í ¹æÇ⼺(Û»úÅàõ)ÀÇ ¹«»ö °áÁ¤Ã¼ÀÌ´Ù.

(D) °ú»êÈ­¾ËÄÚ¿Ã(alcohol peroxide), °ú»êÈ­¿¡Å׸£(ether peroxide), °ú»êÈ­¾Æ¼¼Å»(acetal peroxide)¡¤°ú»êÈ­Çì¹Ì¾Æ¼¼Å»(hemiacetal peroxide)°ú °ú»êÈ­ÄÉÅæ(ketone peroxide)
À̰͵éÀº ROOH, ROOR©ö °è¿­ÀÇ È­ÇÕ¹°·Î¼­, R°ú R©öÀº À¯±â±â(êóѦÐñ : organic radical)ÀÌ´Ù.
±× ¿¹·Î´Â °ú»êÈ­È÷µå·Î¿¡Æ¿°ú °ú»êÈ­µð¿¡Æ¿ÀÌ ÀÖ´Ù.
ÀÌ È£¿¡´Â ¶ÇÇÑ °ú»êÈ­ÄÉÅæ(ketone peroxides)(È­ÇÐÀûÀ¸·Î ´ÜÀÏÇÑ °ÍÀÎÁö¿¡ »ó°ü¾ø´Ù)[¿¹: °ú»êÈ­½ÃŬ·ÎÇí»ç³í(1-È÷µå·ÎÆä·Ï½Ã½ÃŬ·ÎÇí½Ç-1-È÷µå·Ï½Ã½ÃŬ·ÎÇí½Ç Æä·Ï»çÀ̵å)(cyclohexanone peroxide(1-hydroperoxycyclohexyl-1-hydroxycyclohexyl peroxide))* »Ó¸¸ ¾Æ´Ï¶ó, °ú»êÈ­¾Æ¼¼Å»°ú °ú»êÈ­Çì¹Ì¾Æ¼¼Å»[ÆÛ¿Á½ÃÄÉÅ»(peroxyketal)À» Æ÷ÇÔÇÑ´Ù][¿¹: 1,1-µð(ÅͼŸ®-ºÎÆ¿Æä·Ï½Ã)½ÃŬ·ÎÇí»ê]*À» ºÐ·ùÇÑ´Ù.


ÀÌ È£¿¡´Â ¿¡Å׸£(ether)¡¤¿¡Å׸£¾ËÄÚ¿Ã(ether-alochol)¡¤¿¡Å׸£Æä³î(ether-phenol)¡¤¿¡Å׸£¾ËÄÚ¿ÃÆä³î(ether-alcohol-phenol)¡¤°ú»êÈ­¾ËÄÚ¿Ã(alcohol peroxide)¡¤°ú»êÈ­¿¡Å׸£(ether peroxide)³ª °ú»êÈ­ÄÉÅæ(ketone peroxide)ÀÇ ÇҷΰÕÈ­(halogenated)À¯µµÃ¼¡¤¼úÆùÈ­(sulphonated)À¯µµÃ¼¡¤´ÏÆ®·ÎÈ­(nitrated)À¯µµÃ¼¡¤´ÏÆ®·Î¼ÒÈ­(nitrosated)À¯µµÃ¼¿Í º¹ÇÕÀ¯µµÃ¼[¿¹: ´ÏÆ®·Î¼úÆùÈ­(nitrosulphonated)À¯µµÃ¼¡¤¼úÆùÇҷΰÕÈ­(sulphohalogenated)À¯µµÃ¼¡¤´ÏÆ®·ÎÇҷΰÕÈ­(nitrohalogenated)À¯µµÃ¼¿Í ´ÏÆ®·Î¼úÆ÷ÇҷΰÕÈ­(nitrosulphohalogenated)À¯µµÃ¼]¸¦ ºÐ·ùÇÑ´Ù.
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